Factional Overview

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Here's the Currently known Factions, and the characters available to each:

Masters of the universe - 
He-Man
Ram Man
Man at Arms
Orko
Stratos
Teela
Sorceress
Buzz Off
Man-E-Faces
Fisto
Palace Guards
He-Man with Battle Cat

Evil Warriors - 
Skeletor
Evil-Lyn
Mer Man
Trap Jaw
Tri-Klops
Beast Man
Scareglow
Stinkor
Whiplash
Hover Robot
Webstor
Skeletor with Panthor

Evil Horde - 
Hordak
Catra
Grizzlor
Horde Troopers
Horde Wraiths
Shadow Weaver
Leech
Scorpia
Hordak on Mantisaur

Great Rebellion - 
She-Ra
Glimmer
Frosta
Castaspella
Bow
Angella
She-Ra with Swiftwind

Snake Men - 
King Hsss
Fang-Or
Sssqueeze
Kobra Khan
Lady Slither
Rattlor
King Hsss with Tyrantisaurus

Preternian Heros - 
King Grayskull
Veena
He-Ro
Eldor
Zodac
He-Ro II
Bionatops
Zodac with Throne

Fighting Foes - (Factionless, can be included in any force)
Dawg-o-Tor in Battle Ram